Conversion of (-)-3-Dehydroshikimic Acid into Derivatives of the (+)-Enantiomer
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Banwell, Martin; Edwards, Alison; Essers, Michael; Jolliffe, Katrina
Description
(-)-3-DHS (1), a compound available in large quantity through "engineering" of the shikimic acid pathway, has been converted over eight steps into the methyl ester, ent-2, of the (+)-enantiomer. Methyl (+)-shikimate (15) and its C-3 epimer (ent-5) have also been prepared by related means.
Collections | ANU Research Publications |
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Date published: | 2003 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/88395 |
Source: | Journal of Organic Chemistry |
DOI: | 10.1021/jo034689c |
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