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Bridgehead Arylation: A Direct Route to Advanced Intermediates for the Synthesis of C-20 Diterpene Alkaloids

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Williams, Craig; Mander, Lewis

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Equation presented. Rapid access to the ABCE ring system of the C 20 diterpene alkaloids was achieved by silver(I)-promoted intramolecular Friedel-Crafts arylation of a functional group-specific 5-bromo-3-azabicyclo[3.3.1]nonane derivative.

dc.contributor.authorWilliams, Craig
dc.contributor.authorMander, Lewis
dc.date.accessioned2015-12-13T23:13:58Z
dc.date.available2015-12-13T23:13:58Z
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/1885/88379
dc.description.abstractEquation presented. Rapid access to the ABCE ring system of the C 20 diterpene alkaloids was achieved by silver(I)-promoted intramolecular Friedel-Crafts arylation of a functional group-specific 5-bromo-3-azabicyclo[3.3.1]nonane derivative.
dc.publisherAmerican Chemical Society
dc.sourceOrganic Letters
dc.subjectKeywords: alkaloid derivative; alkane derivative; carbon; silver; article; arylation; chemical reaction; chemical structure; drug structure; drug synthesis; Friedel crafts arylation; Acylation; Alkaloids; Aza Compounds; Bridged Compounds; Bromides; Catalysis; Cycli
dc.titleBridgehead Arylation: A Direct Route to Advanced Intermediates for the Synthesis of C-20 Diterpene Alkaloids
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume5
dc.date.issued2003
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationMigratedxPub18058
local.type.statusPublished Version
local.contributor.affiliationWilliams, Craig, University of Queensland
local.contributor.affiliationMander, Lewis, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.issue19
local.bibliographicCitation.startpage3499
local.bibliographicCitation.lastpage3502
local.identifier.doi10.1021/ol0353060
dc.date.updated2015-12-12T08:36:31Z
local.identifier.scopusID2-s2.0-0344392771
CollectionsANU Research Publications

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