(Ethene)bis(acetylacetonato) complexes of divalent and trivalent ruthenium
Zinc dust reduction of tris(acetylacetonato)ruthenium(III), [Ru(acac)3], in hot aqueous THF in the presence of ethene gives cis-[Ru(acac)2(η2-C2H4)2 ] (5), isolated as an orange solid in ca. 60% yield. A single-crystal X-ray crystallographic study shows
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