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Spin transition centres linked by the nitroprusside ion. The cooperative transition in bis(2,6-bis(pyrazol-3-yl)pyridine)iron(II) nitroprusside

Sugiyarto, Kristian; McHale, Wendy-Anne; Craig, Donald C; Rae, A David; Scudder, Marcia; Goodwin, Harold

Description

The complex [Fe(3-bpp)2][Fe(CN)5(NO)] (3-bpp = 2,6-bis(pyrazol-3-yl)pyridine) undergoes an abrupt, thermally-induced 1A1 ↔ 5T2 spin transition associated with a narrow (∼3 K) hysteresis loop (T1/2↓ = 181 K; T1/2 = ↑ 84 K). The transition is accomp

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/87854
Source: Dalton Transactions
DOI: 10.1039/b301218b

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