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Homoanomeric effect in the 1,2-dimethoxyethyl radical

Henry, David; Beckmann, Annalise; Radom, Leo

Description

A homoanomeric effect is found to stabilize the 1,2-dimethoxyethyl radical (CH3O-C•H-CH2OCH3) in a conformation in which the singly-occupied orbital at the radical centre is approximately coplanar with the p-type lone pair on the α-oxygen and with the

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/87828
Source: Australian Journal of Chemistry
DOI: 10.1071/CH02255

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