Homoanomeric effect in the 1,2-dimethoxyethyl radical
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Henry, David; Beckmann, Annalise; Radom, Leo
Description
A homoanomeric effect is found to stabilize the 1,2-dimethoxyethyl radical (CH3O-C•H-CH2OCH3) in a conformation in which the singly-occupied orbital at the radical centre is approximately coplanar with the p-type lone pair on the α-oxygen and with the
Collections | ANU Research Publications |
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Date published: | 2003 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/87828 |
Source: | Australian Journal of Chemistry |
DOI: | 10.1071/CH02255 |
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