Homoanomeric effect in the 1,2-dimethoxyethyl radical
A homoanomeric effect is found to stabilize the 1,2-dimethoxyethyl radical (CH3O-C•H-CH2OCH3) in a conformation in which the singly-occupied orbital at the radical centre is approximately coplanar with the p-type lone pair on the α-oxygen and with the
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|Source:||Australian Journal of Chemistry|
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