Skip navigation
Skip navigation
A change is coming. Click to see a sneak peek of the new Open Research Repository.

Mixed-metal cluster chemistry. 23. Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters linked by heterocyclic groups

link to publisher version

  • Altmetric Citations

Notaras, Eleni; Lucas, Nigel; Willis, Anthony; Rae, A David; Humphrey, Mark

Description

Reaction between the tetrahedral cluster compound Mo2Ir 2(CO)10(η5-C5H 4Me)2 (1) and 2-iodo-5-(oct-1′-ynyl)thiophene afforded the pseudooctahedral cluster Mo2Ir2{U 4-n2Me(CH2)5C2-5-C4H 2S-2-I}(CO)8(n5-C5H 4Me)2 (17) by formal insertion of the alkyne C�

dc.contributor.authorNotaras, Eleni
dc.contributor.authorLucas, Nigel
dc.contributor.authorWillis, Anthony
dc.contributor.authorRae, A David
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-13T23:11:57Z
dc.date.available2015-12-13T23:11:57Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/87824
dc.description.abstractReaction between the tetrahedral cluster compound Mo2Ir 2(CO)10(η5-C5H 4Me)2 (1) and 2-iodo-5-(oct-1′-ynyl)thiophene afforded the pseudooctahedral cluster Mo2Ir2{U 4-n2Me(CH2)5C2-5-C4H 2S-2-I}(CO)8(n5-C5H 4Me)2 (17) by formal insertion of the alkyne C�
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Chemical bonds; Cyclic voltammetry; Electrochemistry; Isomers; Oxidation; Single crystals; X ray diffraction; Ligands; Reaction kinetics
dc.titleMixed-metal cluster chemistry. 23. Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters linked by heterocyclic groups
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume22
dc.date.issued2003
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub17281
local.type.statusPublished Version
local.contributor.affiliationNotaras, Eleni, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLucas, Nigel, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationRae, A David, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.issue18
local.bibliographicCitation.startpage3659
local.bibliographicCitation.lastpage3670
local.identifier.doi10.1021/om030253b
dc.date.updated2015-12-12T08:29:48Z
local.identifier.scopusID2-s2.0-0041823197
CollectionsANU Research Publications

Download

There are no files associated with this item.
Show simple item record


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  17 November 2022/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator