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Mixed-metal cluster chemistry. 23. Synthesis and crystallographic and electrochemical studies of alkyne-coordinated group 6-iridium clusters linked by heterocyclic groups

Notaras, Eleni; Lucas, Nigel; Willis, Anthony; Rae, A David; Humphrey, Mark


Reaction between the tetrahedral cluster compound Mo2Ir 2(CO)10(η5-C5H 4Me)2 (1) and 2-iodo-5-(oct-1′-ynyl)thiophene afforded the pseudooctahedral cluster Mo2Ir2{U 4-n2Me(CH2)5C2-5-C4H 2S-2-I}(CO)8(n5-C5H 4Me)2 (17) by formal insertion of the alkyne C�

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Organometallics
DOI: 10.1021/om030253b


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