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Solid State Synthesis, Structure and Optical Limiting Properties of Seleno Cuboidal Clusters [M3Se4X3(diphosphine)3]+(M=Mo,W,X=Cl, Br)

Feliz, Marta; Llusar, Rosa; Uriel, Santiago; Vicent, Cristian; Lucas, Nigel; Samoc, Marek; Luther-Davies, Barry; Humphrey, Mark


The trinuclear complexes [M3(μ3-Se)(μ-Se)3X3(dppe) 3]PF6 [M=Mo, X=Cl (1), Br (2); M=W, X=Br (3)] have been prepared by both solid state and solution syntheses. A structural study of 1 confirms the presence of an incomplete cuboidal Mo3Se4 core. The elec

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Inorganica Chimica Acta
DOI: 10.1016/S0020-1693(03)00089-6


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