Organometallic Complexes for Nonlinear Optics. 30. Electrochromic Linear and Nonlinear Optical Properties of Alkynylbis(diphosphine)ruthenium Complexes
A combination of cyclic voltammetry, UV-vis-NIR spectroelectrochemistry, time-dependent density functional theory (TD-DFT), and Z-scan measurements employing a modified optically transparent thin-layer electrochemical (OTTLE) cell has been used to identify and assign intense transitions of metal alkynyl complexes at technologically important wavelengths in the oxidized state and to utilize these transitions to demonstrate a facile electrochromic switching of optical nonlinearity. Cyclic...[Show more]
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