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The first structurally characterised perchlorato-cobalt(III) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane

Zhou, Xiangting; Day, Anthony; Willis, Anthony; Jackson, William Gregory

Description

Two isomeric C-bonded complexes, sym-anti-[Co(L-C)(OH2)] 2+ and sym-syn-[Co(L-C)(OH2)]2+ (L = 1,4,8,11-tetraazabicyclo[9.5.2]octadecane) when crystallised from aqueous NaClO4 remarkably yielded the corresponding perchlorato complexes, confirmed by the single crystal X-ray structures.

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/87690
Source: Chemical Communications

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