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Expect the unexpected. Isolation and characterisation of some unusual organometallic gold(I) complexes

Bhargava, Suresh Kumar; Mohr, Fabian; Willis, Anthony

Description

The reaction of equimolar amounts of 2-Li-3-MeC6H3PPh2 and [AuBr(AsPh3)] gives a mixture of the cyclometallated digold(I) complex [Au2(μ-6-MeC6H3-2-PPh2) 2] and the 'half-cyclometallated' complex [(Ph3As)Au(μ-6-MeC6H3-2-PPh 2)AuBr] (1). This complex rep

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/87686
Source: Inorganica Chimica Acta
DOI: 10.1016/S0020-1693(03)00128-2

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