Expect the unexpected. Isolation and characterisation of some unusual organometallic gold(I) complexes
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Bhargava, Suresh Kumar; Mohr, Fabian; Willis, Anthony
Description
The reaction of equimolar amounts of 2-Li-3-MeC6H3PPh2 and [AuBr(AsPh3)] gives a mixture of the cyclometallated digold(I) complex [Au2(μ-6-MeC6H3-2-PPh2) 2] and the 'half-cyclometallated' complex [(Ph3As)Au(μ-6-MeC6H3-2-PPh 2)AuBr] (1). This complex rep
Collections | ANU Research Publications |
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Date published: | 2003 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/87686 |
Source: | Inorganica Chimica Acta |
DOI: | 10.1016/S0020-1693(03)00128-2 |
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