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Organometallic Complexes for Nonlinear Optics. 33. Electrochemical Switching of the Third-order Nonlinearity Observed by Simultaneous Femtosecond Degenerate Four-wave Mixing and Pump-probe Measurements

Powell, Clem; Cifuentes, Marie; Morrall, Joseph; Samoc, Marek; Luther-Davies, Barry; Humphrey, Mark


The molecular inorganic compound 1,3,5-{trans-[RuCl(dppe) 2]C≡C-4-C6H4C≡C}3C 6H3 (1) is reversibly oxidized in solution using an optically transparent thin-layer electrochemical (OTTLE) cell, the oxidation to 13+ resulting in the appearance of a stron

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Journal of Physical Chemistry A
DOI: 10.1021/jp0366217


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