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Organometallic complexes for nonlinear optics. Part 27. Syntheses and optical properties of some iron, ruthenium and osmium alkynyl complexes

Powell, Clem; Cifuentes, Marie; McDonagh, Andrew; Hurst, Stephanie; Lucas, Nigel; Delfs, Christopher; Stranger, Robert; Houbrechts, Stephan; Asselberghs, Inge; Persoons, Andre Pierre; Hockless, David; Humphrey, Mark

Description

The syntheses of the alkynyl complexes M(4-C≡CC6H4NO2)(dppe)(η-C 5H5) [M=Fe (1), Ru (2), Os (3)], Os(4-C≡CC6H4NO2)(PPh3) 2(η-C5H5) (4) and Ru(4-C≡CC6H4NO2)(CO)2 (η-C5H5) (5) are reported. Structural studies reveal a decrease in Ru-C(1) distance o

dc.contributor.authorPowell, Clem
dc.contributor.authorCifuentes, Marie
dc.contributor.authorMcDonagh, Andrew
dc.contributor.authorHurst, Stephanie
dc.contributor.authorLucas, Nigel
dc.contributor.authorDelfs, Christopher
dc.contributor.authorStranger, Robert
dc.contributor.authorHoubrechts, Stephan
dc.contributor.authorAsselberghs, Inge
dc.contributor.authorPersoons, Andre Pierre
dc.contributor.authorHockless, David
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-13T23:11:38Z
dc.date.available2015-12-13T23:11:38Z
dc.identifier.issn0020-1693
dc.identifier.urihttp://hdl.handle.net/1885/87674
dc.description.abstractThe syntheses of the alkynyl complexes M(4-C≡CC6H4NO2)(dppe)(η-C 5H5) [M=Fe (1), Ru (2), Os (3)], Os(4-C≡CC6H4NO2)(PPh3) 2(η-C5H5) (4) and Ru(4-C≡CC6H4NO2)(CO)2 (η-C5H5) (5) are reported. Structural studies reveal a decrease in Ru-C(1) distance o
dc.publisherElsevier
dc.sourceInorganica Chimica Acta
dc.subjectKeywords: alkynyl group; biphenyl; carbonyl derivative; iron complex; ligand; metal; organometallic compound; osmium derivative; phosphine derivative; ruthenium complex; analytic method; article; calculation; chemical model; chemical structure; crystallography; dat Alkynyl; Cyclic voltammetry; Density functional theory; Iron; NLO; Osmium; Ruthenium; X-ray structure
dc.titleOrganometallic complexes for nonlinear optics. Part 27. Syntheses and optical properties of some iron, ruthenium and osmium alkynyl complexes
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume352
dc.date.issued2003
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub17052
local.type.statusPublished Version
local.contributor.affiliationPowell, Clem, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCifuentes, Marie, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMcDonagh, Andrew, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHurst, Stephanie, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLucas, Nigel, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationDelfs, Christopher, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationStranger, Robert, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHoubrechts, Stephan, Catholic University of Leuven
local.contributor.affiliationAsselberghs, Inge, Catholic University of Leuven
local.contributor.affiliationPersoons, Andre Pierre, Catholic University of Leuven
local.contributor.affiliationHockless, David, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.startpage9
local.bibliographicCitation.lastpage18
local.identifier.doi10.1016/S0020-1693(03)00126-9
dc.date.updated2015-12-12T08:28:16Z
local.identifier.scopusID2-s2.0-0043200952
CollectionsANU Research Publications

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