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Organometallic complexes for nonlinear optics. Part 27. Syntheses and optical properties of some iron, ruthenium and osmium alkynyl complexes

Powell, Clem; Cifuentes, Marie; McDonagh, Andrew; Hurst, Stephanie; Lucas, Nigel; Delfs, Christopher; Stranger, Robert; Houbrechts, Stephan; Asselberghs, Inge; Persoons, Andre Pierre; Hockless, David; Humphrey, Mark


The syntheses of the alkynyl complexes M(4-C≡CC6H4NO2)(dppe)(η-C 5H5) [M=Fe (1), Ru (2), Os (3)], Os(4-C≡CC6H4NO2)(PPh3) 2(η-C5H5) (4) and Ru(4-C≡CC6H4NO2)(CO)2 (η-C5H5) (5) are reported. Structural studies reveal a decrease in Ru-C(1) distance o

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Inorganica Chimica Acta
DOI: 10.1016/S0020-1693(03)00126-9


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