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A unique mechanism for base catalyzed hydrolysis of pentaaminecobalt(III) complexes containing picolyl residues

Dickie, Alistair J; Hockless, David; Willis, Anthony; McKeon, Josephine A; Jackson, William Gregory

Description

A novel [Co(pentaamine)CI]2+ complex having all tertiary amine or pyridine donors has been synthesized (pentaamine = 1,4-bis(2′-pyridyl)-7-methyl-1,4,7-triazacyclononane). This asym-[Co(dmpmetacn)Cl]2+ species has been completely characterized through 1

dc.contributor.authorDickie, Alistair J
dc.contributor.authorHockless, David
dc.contributor.authorWillis, Anthony
dc.contributor.authorMcKeon, Josephine A
dc.contributor.authorJackson, William Gregory
dc.date.accessioned2015-12-13T23:11:37Z
dc.date.available2015-12-13T23:11:37Z
dc.identifier.issn0020-1669
dc.identifier.urihttp://hdl.handle.net/1885/87668
dc.description.abstractA novel [Co(pentaamine)CI]2+ complex having all tertiary amine or pyridine donors has been synthesized (pentaamine = 1,4-bis(2′-pyridyl)-7-methyl-1,4,7-triazacyclononane). This asym-[Co(dmpmetacn)Cl]2+ species has been completely characterized through 1
dc.publisherAmerican Chemical Society
dc.sourceInorganic Chemistry
dc.subjectKeywords: amine; base; carbene; cobalt [1,4 bis(2' pyridyl) 7 methyl 1,4,7 triazacyclononane]; cobalt complex; unclassified drug; amination; article; catalysis; catalyst; chemical structure; hydrolysis; nuclear magnetic resonance; proton transport; reaction analysi
dc.titleA unique mechanism for base catalyzed hydrolysis of pentaaminecobalt(III) complexes containing picolyl residues
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume42
dc.date.issued2003
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationMigratedxPub17043
local.type.statusPublished Version
local.contributor.affiliationDickie, Alistair J, University of New South Wales, ADFA
local.contributor.affiliationHockless, David, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMcKeon, Josephine A, University of New South Wales, ADFA
local.contributor.affiliationJackson, William Gregory, University of New South Wales, ADFA
local.bibliographicCitation.issue12
local.bibliographicCitation.startpage3822
local.bibliographicCitation.lastpage3834
local.identifier.doi10.1021/ic0206995
dc.date.updated2015-12-12T08:28:13Z
local.identifier.scopusID2-s2.0-0037607295
CollectionsANU Research Publications

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