A unique mechanism for base catalyzed hydrolysis of pentaaminecobalt(III) complexes containing picolyl residues
A novel [Co(pentaamine)CI]2+ complex having all tertiary amine or pyridine donors has been synthesized (pentaamine = 1,4-bis(2′-pyridyl)-7-methyl-1,4,7-triazacyclononane). This asym-[Co(dmpmetacn)Cl]2+ species has been completely characterized through 1
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