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Hydrotris-(methimazolyl)borato alkylidyne complexes of tungsten

Foreman, Mark; Hill, Anthony; White, Andrew G; Williams, David

Description

The syntheses of the alkylidyne complexes [W(≡CR)(CO)2{HB(mt)3}] (R = NiPr2 1a, C4H3S-2 1b, C≡CCMe3 1c, C6H4Me-4 1d, C6H3Me2-2,6 1e, C5H4Mn(CO)3 1f; mt = 2-mercapto-3-methylimidazolyl) are reported. The crystal structures of three examples (1a, 1b, an

dc.contributor.authorForeman, Mark
dc.contributor.authorHill, Anthony
dc.contributor.authorWhite, Andrew G
dc.contributor.authorWilliams, David
dc.date.accessioned2015-12-13T23:11:37Z
dc.date.available2015-12-13T23:11:37Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/87665
dc.description.abstractThe syntheses of the alkylidyne complexes [W(≡CR)(CO)2{HB(mt)3}] (R = NiPr2 1a, C4H3S-2 1b, C≡CCMe3 1c, C6H4Me-4 1d, C6H3Me2-2,6 1e, C5H4Mn(CO)3 1f; mt = 2-mercapto-3-methylimidazolyl) are reported. The crystal structures of three examples (1a, 1b, an
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Chelation; Complexation; Conformations; Crystal structure; Crystal symmetry; Nuclear magnetic resonance spectroscopy; Tungsten compounds; Hydrotris methimazolyl borato alkylidyne; Octahedral coordination; Symmetric conformation; Organometallics
dc.titleHydrotris-(methimazolyl)borato alkylidyne complexes of tungsten
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume22
dc.date.issued2003
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub17039
local.type.statusPublished Version
local.contributor.affiliationForeman, Mark, Imperial College London
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWhite, Andrew G, University of Queensland
local.contributor.affiliationWilliams, David, Imperial College London
local.bibliographicCitation.issue19
local.bibliographicCitation.startpage3831
local.bibliographicCitation.lastpage3840
local.identifier.doi10.1021/om030288b
dc.date.updated2015-12-12T08:28:12Z
local.identifier.scopusID2-s2.0-0141507877
CollectionsANU Research Publications

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