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Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

Caldwell, Lorraine; Edwards, Alison; Hill, Anthony; Neumann, Horst; Schultz, Madeleine


The reaction of 4,7,10-trithiatrideca-2,11-diyne with RhCl(PPh3)3 results in cleavage and rearrangement of the diyne with formation of the structurally characterized complex RhCl(C≡CMe)(PPh3){κ3-S,S′,S″-S(CH= CH2)CH2CH2SCH=CMeS}.

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Organometallics
DOI: 10.1021/om030040m


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