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Mixed-metal cluster chemistry. 27. Coupling of diphenylbuta-1,3-diyne and CO at tungsten-triiridium cluster cores

Dalton, Gulliver; Willis, Anthony; Humphrey, Mark

Description

Reactions of WIr3(CO)11(η-C5H 4R) (R=H, Me) and excess diphenylbuta-1,3-diyne in refluxing toluene afford a large number of products in each case, one of which has been identified as [WIr3{μ 4-η 7-C(Ph)C(C≡ CPh)C(Ph)CC(H)CC6H4 C(O)-2}(CO)7(η-C 5H4R)

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
URI: http://hdl.handle.net/1885/86996
Source: Journal of Cluster Science
DOI: 10.1023/B:JOCL.0000041196.07154.9f

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