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Synthesis, characterization, and electrochemical relationships of dinuclear complexes of platinum(II) and platinum(III) containing ortho-metalated tertiary arsine ligands

Bennett, Martin; Bhargava, Suresh Kumar; Bond, I A; Edwards, Alison; Guo, Si-Xuan; Priver, Steven H; Rae, A David; Willis, Anthony

Description

Reaction of 2-Li-4-MeC6H3AsPh2 with [PtCl2(SEt2)2] gives two isomeric dinuclear platinum(II) complexes, one containing a half-lantern structure with two chelating and two bridging C6H3-5-Me-2-AsPh2 ligands, [Pt2(κ2As,C-C6H 3-5-Me-2-AsPh2)2(μ-κAs,κC-C

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
URI: http://hdl.handle.net/1885/86829
Source: Inorganic Chemistry
DOI: 10.1021/ic0498790

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