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The first rhodaboratrane: [RhCl(PPh 3 ){B(mt) 3 }]( Rh→B ) (mt = methimazolyl)

Crossley, Ian R; Foreman, Mark; Hill, Anthony; White, Andrew G; Williams, David

Description

The reaction of [Rh(C6H5)Cl2(PPh 3)2] with Na[HB(mt)3] (mt = methimazolyl) provides [RhCl(PPh3){B(mt)3}](Rh→B) the first authentic example of a compound with a rhodium-boron dative bond.

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/86827
Source: Chemical Communications
DOI: 10.1039/b413305f

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