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Bi- and tetranuclear tricarbido complexes: μ,σ:σ' and μ,σ:σ':π ⊥ coordination of bridging C 3 ligands

Dewhurst, Rian; Hill, Anthony; Willis, Anthony

Description

Fluoride-mediated desilylation of the propargylidyne [W(≡CC≡CSiMe3)(CO)2{HB(Pz)3}] (1; pz = pyrazol-1-yl) in the presence of [RhCl(CO)(PPh3)2] provides the bimetallic complex [Rh(C≡C≡W(CO) 2{HB-(pz)3})(CO)(PPh3)2] (2b), which reacts with iodine to

dc.contributor.authorDewhurst, Rian
dc.contributor.authorHill, Anthony
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-13T23:09:00Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/86820
dc.description.abstractFluoride-mediated desilylation of the propargylidyne [W(≡CC≡CSiMe3)(CO)2{HB(Pz)3}] (1; pz = pyrazol-1-yl) in the presence of [RhCl(CO)(PPh3)2] provides the bimetallic complex [Rh(C≡C≡W(CO) 2{HB-(pz)3})(CO)(PPh3)2] (2b), which reacts with iodine to
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Carbon; Chromatographic analysis; Organometallics; Oxidation; Resonance; Rhodium; Synthesis (chemical); Desilylation; Dichloromethane solution; Molecular geometry; Trcarbido complexes; Complexation
dc.titleBi- and tetranuclear tricarbido complexes: μ,σ:σ' and μ,σ:σ':π ⊥ coordination of bridging C 3 ligands
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume23
dc.date.issued2004
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub15844
local.type.statusPublished Version
local.contributor.affiliationDewhurst, Rian, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue25
local.bibliographicCitation.startpage5903
local.bibliographicCitation.lastpage5906
local.identifier.doi10.1021/om0401152
dc.date.updated2015-12-12T08:17:09Z
local.identifier.scopusID2-s2.0-10644259665
CollectionsANU Research Publications

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