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Bi- and tetranuclear tricarbido complexes: μ,σ:σ' and μ,σ:σ':π ⊥ coordination of bridging C 3 ligands

Dewhurst, Rian; Hill, Anthony; Willis, Anthony

Description

Fluoride-mediated desilylation of the propargylidyne [W(≡CC≡CSiMe3)(CO)2{HB(Pz)3}] (1; pz = pyrazol-1-yl) in the presence of [RhCl(CO)(PPh3)2] provides the bimetallic complex [Rh(C≡C≡W(CO) 2{HB-(pz)3})(CO)(PPh3)2] (2b), which reacts with iodine to

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
URI: http://hdl.handle.net/1885/86820
Source: Organometallics
DOI: 10.1021/om0401152

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