Reactions of ruthenium(0) phosphine complexes with diphenylacetylene
Heating diphenylacetylene with [Ru(CO)2(PPh3) 3] in toluene under reflux provides the 2-phenylindenone complex [Ru(η3=CCPh=CHC6H4)(CO)(PPh 3)2], arising from C-H activation of one ortho-proton of diphenylacetylene, hydroruthenation of the triple bond, an
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