Di- and zerovalent platinaboratranes: The first pentacoordinate d 10 platinum(0) complex
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Crossley, Ian R; Hill, Anthony
Description
The reaction of [PtCl2(PPh3)2 with Na[H-B(mt)3] (mt = methimazolyl) affords the platinaboratrane salt [PtH(PPh3){B(mt)3}]Cl(PtII→B), the first example of a metallaboratrane with the metal center in the +2 oxidation state. Base-induced dehydrochlorina-ti
Collections | ANU Research Publications |
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Date published: | 2004 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/86800 |
Source: | Organometallics |
DOI: | 10.1021/om040114 |
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