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Di- and zerovalent platinaboratranes: The first pentacoordinate d 10 platinum(0) complex

Crossley, Ian R; Hill, Anthony


The reaction of [PtCl2(PPh3)2 with Na[H-B(mt)3] (mt = methimazolyl) affords the platinaboratrane salt [PtH(PPh3){B(mt)3}]Cl(PtII→B), the first example of a metallaboratrane with the metal center in the +2 oxidation state. Base-induced dehydrochlorina-ti

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: Organometallics
DOI: 10.1021/om040114


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