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The coordination chemistry of the pentadentate 2,2,6,6-tetrakis(aminomethyl)-4-azaheptane (ditame)

Hegetschweiler, Kaspar; Maas, Oliver; Zimmer, Anja; Geue, Rodney; Sargeson, Alan; Harmer, Jeffrey; Schweiger, Arthur; Buder, Irmgard; Schwitzgebel, Gunter; Reiland, Vera; Frank, Walter

Description

The protonation and metal complex formation of the branched pentaamine ligand 2,2,6,6-tetrakis(aminomethyl)-4-azaheptane (ditame, L) with CoII, CoIII, NII, CuII, ZnII, and CDII have been studied. The crystal structures of [Ni(ditame)(EtOH)] Br2, [CO2(ditame)2(O2)Cl4 ·4H2O, and [Co2-(ditame)2(O2)]Cl2 [ZnCl4][ZnCl3(H2O)]·H2O were determined by X-ray diffraction analyses. The metal complexes showed octahedral coordination geometries with exclusive formation of six-membered chelate rings, the four...[Show more]

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/86631
Source: European Journal of Inorganic Chemistry

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