Activation and cleavage of dinitrogen by three-coordinate metal complexes involving Mo(III) and Nb(II/III)
Density functional calculations have been employed to rationalize why the heteronuclear N2-bridged MoIIINbIII dimer, [Ar(tBu)N]3Mo(μ-N2)Nb[N(iPr)Ar] 3 (Ar = 3,5-C6H3Me2), does not undergo cleavage of the dinitrogen bridge in contrast to the analogous Mo
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