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Comparison of the Kinetics and Thermodynamics for Methyl Radical Addition to C=C, C=O, and C=S Double Bonds

Henry, David; Coote, Michelle; Gomez-Balderas, Rodolfo; Radom, Leo


The barriers, enthalpies, and rate constants for the addition of methyl radical to the double bonds of a selection of alkene, carbonyl, and thiocarbonyl species (CH2=Z, CH3CH=Z, and (CH 3)2C=Z, where Z = CH2, O, or S) and for the reverse β-scission react

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja039139a


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