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Consistent Experimental and Theoretical Evidence for Long-Lived Intermediate Radicals in Living Free Radical Polymerization

Feldermann, Achim; Coote, Michelle; Stenzel, Martina H; Davis, Thomas P; Barner-Kowollik, Christopher


The cumyl dithiobenzoate (CDB)-mediated reversible addition fragmentation chain transfer (RAFT) polymerization of styrene at 30°C is studied via both kinetic experiments and high-level ab initio molecular orbital calculations. The kinetic data clearly in

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja046292b


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