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Suicide Inactivation of Dioldehydratase by Glycolaldehyde and Chloroacetaldehyde: an Examinaton of the Reaction Mechanism

Sandala, Gregory; Smith, David M; Coote, Michelle; Radom, Leo


High-level ab initio calculations have been used to study the mechanism for the inactivation of diol dehydratase (DDH) by glycolaldehyde or 2-chloroacetaldehyde. As in the case of the catalytic substrates of DDH, e.g., ethane-1,2-diol, the 5′-deoxyadeno

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja047377f


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