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The mechanism of Bu 3 SnH-mediated homolytic aromatic substitution

Beckwith, Athelstan (Athel); Bowry, Vincent W; Bowman, W Russell; Mann, Emma; Parr, Jonathan; Storey, John W


The fate of intermediate π radicals is crucial in Bu 3SnH-mediated cyclization by homolytic aromatic substitution, for example, of bromo compound 1 via radical 2 to give oxindole 3 (AIBN = azobisisobutyronitrile). The results indicate that the mechanism

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: Angewandte Chemie International Edition
DOI: 10.1002/anie.200352419


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