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Modulation of the distance dependence of paramagnetic relaxation enhancements by CSAxDSA cross-correlation

Pintacuda, Guido; Kaikkonen, Andrei; Otting, Gottfried

Description

Paramagnetic metal ions with fast-relaxing electronic spin and anisotropic susceptibility tensor provide a rich source of structural information that can be derived from pseudo-contact shifts, residual dipolar couplings, dipole-dipole Curie spin cross-correlation, and paramagnetic relaxation enhancements. The present study draws attention to a cross-correlation effect between nuclear relaxation due to anisotropic chemical shielding (CSA) and due to the anisotropic dipolar shielding (DSA) caused...[Show more]

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
URI: http://hdl.handle.net/1885/85978
Source: Journal of Magnetic Resonance
DOI: 10.1016/j.jmr.2004.08.019

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