Modulation of the distance dependence of paramagnetic relaxation enhancements by CSAxDSA cross-correlation
Paramagnetic metal ions with fast-relaxing electronic spin and anisotropic susceptibility tensor provide a rich source of structural information that can be derived from pseudo-contact shifts, residual dipolar couplings, dipole-dipole Curie spin cross-correlation, and paramagnetic relaxation enhancements. The present study draws attention to a cross-correlation effect between nuclear relaxation due to anisotropic chemical shielding (CSA) and due to the anisotropic dipolar shielding (DSA) caused...[Show more]
|Collections||ANU Research Publications|
|Source:||Journal of Magnetic Resonance|
|01_Pintacuda_Modulation_of_the_distance_2004.pdf||832.23 kB||Adobe PDF||Request a copy|
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