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Convolutive modelling of the disk electrode geometry under reversible conditions

Mahon, Peter; Oldham, Keith


The disk electrode is one of the most readily constructed electrode geometries but the perimetric discontinuity complicates the theoretical analysis. Under reversible conditions, this system simplifies to a situation that can be described by a convolution expression and can therefore be modelled by the method known as convolutive modelling. Convolutive modelling is here employed to simulate cyclic voltammograms at a disk electrode; those results are compared to fast quasi-explicit finite...[Show more]

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
Source: Electrochimica Acta
DOI: 10.1016/j.electacta.2004.07.018


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