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Synthesis and structure determination of three new 12β-hydroxy C 20 gibberellins (GA 127 , GA 128 and GA 129 )

Leitch, Sarah; Blake, Patrick; Mander, Lewis

Description

Three new 12β-hydroxylated C20 gibberellins have been isolated from strawberry fruitlets and their structures confirmed by synthesis from gibberellic acid. The key stages in the synthesis involved transannular hydroxylation using diacetoxy iodobenzene an

dc.contributor.authorLeitch, Sarah
dc.contributor.authorBlake, Patrick
dc.contributor.authorMander, Lewis
dc.date.accessioned2015-12-13T23:06:02Z
dc.date.available2015-12-13T23:06:02Z
dc.identifier.issn1551-7004
dc.identifier.urihttp://hdl.handle.net/1885/85832
dc.description.abstractThree new 12β-hydroxylated C20 gibberellins have been isolated from strawberry fruitlets and their structures confirmed by synthesis from gibberellic acid. The key stages in the synthesis involved transannular hydroxylation using diacetoxy iodobenzene an
dc.publisherARKAT Foundation
dc.sourceARKIVOC
dc.subjectKeywords: diacetoxyiodobenzene; gibberellic acid; gibberellin; gibberellin 127; gibberellin 128; gibberellin 129; iodobenzene; unclassified drug; aerobic metabolism; article; chemical structure; fruit; hydroxylation; reaction analysis; strawberry; structure analysi Diacetoxy iodobenzene; Enolate; Gibberellin; Oxidative cleavage; Strawberry; Transannular hydroxylation
dc.titleSynthesis and structure determination of three new 12β-hydroxy C 20 gibberellins (GA 127 , GA 128 and GA 129 )
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
dc.date.issued2003
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationMigratedxPub14496
local.type.statusPublished Version
local.contributor.affiliationLeitch, Sarah, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBlake, Patrick, Horticulture Research International
local.contributor.affiliationMander, Lewis, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.issue7
local.bibliographicCitation.startpage145
local.bibliographicCitation.lastpage160
dc.date.updated2015-12-12T08:03:24Z
local.identifier.scopusID2-s2.0-3242668740
CollectionsANU Research Publications

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