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CP-225,917 and CP-263,114 Synthesis Support Studies: Testing a Radical Cyclization Strategy for Installation of the Side-Chains

Banwell, Martin; Coster, Mark; Edwards, Alison; Vogtle, Markus

Description

The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).

dc.contributor.authorBanwell, Martin
dc.contributor.authorCoster, Mark
dc.contributor.authorEdwards, Alison
dc.contributor.authorVogtle, Markus
dc.date.accessioned2015-12-13T23:06:00Z
dc.date.available2015-12-13T23:06:00Z
dc.identifier.issn0004-9425
dc.identifier.urihttp://hdl.handle.net/1885/85816
dc.description.abstractThe selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).
dc.publisherCSIRO Publishing
dc.sourceAustralian Journal of Chemistry
dc.subjectKeywords: Free radical reactions; Materials testing; Molecular structure; Negative ions; Stereochemistry; Synthesis (chemical); Allylation sequence; Allyltributylstannane; Hexabutyldistannane hydride; Lactone; Radical cyclization strategy; Selenocarbonate; Side cha
dc.titleCP-225,917 and CP-263,114 Synthesis Support Studies: Testing a Radical Cyclization Strategy for Installation of the Side-Chains
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume56
dc.date.issued2003
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationMigratedxPub14474
local.type.statusPublished Version
local.contributor.affiliationBanwell, Martin, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCoster, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationEdwards, Alison, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationVogtle, Markus, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.issue6
local.bibliographicCitation.startpage577
local.bibliographicCitation.lastpage583
local.identifier.doi10.1071/CH02244
dc.date.updated2015-12-12T08:03:13Z
local.identifier.scopusID2-s2.0-0037810393
CollectionsANU Research Publications

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