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Competitive Intramolecular Diels-Alder Reactions of bis-α,β-Unsaturated Ester Derivatives of Enzymatically Derived and Enantiopure cis -1,2-Dihydrocatechols. Enantiodivergent Synthesis of Monochiral Bicyclo[2.2.2]oct-2-enes

Banwell, Martin; Chun, Chonhoon; Edwards, Alison; Vogtle, Markus

Description

bis-Crotonate and related alpha;,β-unsaturated ester derivatives of readily available and enantiomerically pure cis-1,2-dihydrocatechols engage, upon heating in refluxing toluene, in two competitive intramolecular Diels-Alder reactions to give varying mi

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/85806
Source: Australian Journal of Chemistry
DOI: 10.1071/CH03112

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