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Organometallic complexes for nonlinear optics. Part 36. Quadratic and cubic optical nonlinearities of 4-fluorophenylethynyl- and 4-nitro-( E )-stilbenylethynylruthenium complexes

Morrall, Joseph; Cifuentes, Marie; Kellens, Ruben; Robijns, Elke; Asselberghs, Inge; Clays, Koen Jan; Persoons, Andre Pierre; Samoc, Marek; Willis, Anthony; Humphrey, Mark


The complexes trans-[Ru(CC-4-C6H4F)X(dppe) 2] [X = Cl (1), CCPh (2), CC-4-C6H4NO 2 (3)], trans-[Ru{CC-4-C6H4-(E)-CHCH-4-C 6H4NO2}X(dppe)2] [X = CCPh (4), CC-4-C6H4CCPh (5)], and [C6H 3-1,3-{CC-trans-[RuCl(dppe)2]}2-5-(CC-4-C 6H4F)] (6) have been synthesized and the identity of 1 confirmed by a single-crystal X-ray diffraction study. Cyclic voltammetry reveals a metal-centered oxidation, the potential of which is largely invariant on alkynyl ligand replacement across the series 1-5; the...[Show more]

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: Inorganica Chimica Acta
DOI: 10.1016/j.ica.2005.09.012


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