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Is the Addition-Fragmentation Step of the RAFT Polymerisation Process Chain Length Dependent?

Izgorodina, Ekaterina; Coote, Michelle


The chain length dependence of the addition-fragmentation equilibrium constant (K) for cumyl dithiobenzoate (CDB) mediated polymerisation of styrene has been studied via high level ab initio molecular orbital calculations. The results indicate that chain

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: Macromolecular Theory and Simulations
DOI: 10.1002/mats.200600021


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