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Effect of side chains on competing pathways for β -scission reactions of peptide-backbone alkoxyl radicals

Wood, Geoffrey P F; Easton, Christopher; Rauk, Arvi; Davies, Michael J; Radom, Leo


High-level quantum chemistry calculations have been carried out to investigate β-scission reactions of alkoxyl radicals located at the α-carbon of a peptide backbone. This type of alkoxyl radical may undergo three possible β-scission reactions, namely

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: Journal of Physical Chemistry A
DOI: 10.1021/jp062916j


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