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Chemoenzymatic syntheses of the linear triquinane-type sesquiterpenes (+)-hirsutic acid and (-)-complicatic acid

Jackson, Kerrie; Banwell, Martin; Harfoot, Gwion; Willis, Anthony

Description

Formal total syntheses of the natural enantiomeric forms of the title sesquiterpenes 1 and 2 have been achieved using, as starting material, the readily available and enantiomerically pure cis-1,2-dihydrocatechol 4 derived from the whole-cell biotransformation of toluene.

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
URI: http://hdl.handle.net/1885/85137
Source: Tetrahedron Letters
DOI: 10.1016/j.tetlet.2006.07.145

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