Assembly of the 1-azaspiro[5.5]undecane framework associated with perhydrohistrionicotoxin via electrocyclic ring-opening of a ring-fused gem -dichlorocyclopropane and trapping of the resulting π-allyl cation by a tethered, nitrogen-centered nucleop
Banwell, Martin; Vogt, Odette; Wu, Angela W
The carbamate-tethered gem-dichlorocyclopropane 27 was prepared, as a mixture of epimers, in ten steps from commercially available β,γ-unsaturated nitrile 9. Upon treatment with silver acetate under a range of reaction conditions, compound 27 underwent
|Collections||ANU Research Publications|
|Source:||Australian Journal of Chemistry|
|01_Banwell_Assembly_of_the_2006.pdf||309.29 kB||Adobe PDF||Request a copy|
Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.
Updated: 17 November 2022/ Responsible Officer: University Librarian/ Page Contact: Library Systems & Web Coordinator