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Ortho -metallated transition metal complexes derived from tertiary phosphine and arsine ligands

Mohr, Fabian; Priver, Steven H; Bhargava, Suresh Kumar; Bennett, Martin


This article reviews the synthesis, reactivity and structure of transition metal complexes containing ortho-metallated tertiary phosphines and arsines of the type [2-R2EC6H4]- (E = P, As; R = various substituents). Available synthetic routes are summarized and some general spectroscopic and structural features are discussed. In subsequent sections, ortho-metallated complexes of this type are reviewed, arranged according to the triads of the d-block series. The literature has been covered to the...[Show more]

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: Coordination Chemistry Reviews
DOI: 10.1016/j.ccr.2005.10.003


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