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Swelling of a mesostructured zirconium oxide film

Henderson, Mark; Rennie, Adrian R; Hawley, A; White, John

Description

The structural changes that cause the change in interlayer spacing of a surfactant-templated zirconium oxide film have been studied using neutron diffractometry. We report that the film after drying on a glass substrate swells slightly through the addition of benzene by up to 4 Å on a lattice parameter of about 36 Å. The (0 0 1) and (0 0 2) diffraction peak widths, positions and areas of a swollen film were monitored as a function of benzene desorption. Disorder of the lamellar mesophase is...[Show more]

dc.contributor.authorHenderson, Mark
dc.contributor.authorRennie, Adrian R
dc.contributor.authorHawley, A
dc.contributor.authorWhite, John
dc.date.accessioned2015-12-13T23:03:35Z
dc.identifier.issn0921-4526
dc.identifier.urihttp://hdl.handle.net/1885/85009
dc.description.abstractThe structural changes that cause the change in interlayer spacing of a surfactant-templated zirconium oxide film have been studied using neutron diffractometry. We report that the film after drying on a glass substrate swells slightly through the addition of benzene by up to 4 Å on a lattice parameter of about 36 Å. The (0 0 1) and (0 0 2) diffraction peak widths, positions and areas of a swollen film were monitored as a function of benzene desorption. Disorder of the lamellar mesophase is considered as a cause of the observed effects on the diffraction signals.
dc.publisherElsevier
dc.sourcePhysica B
dc.subjectKeywords: Benzene; Desorption; Neutron diffraction; Surface active agents; Swelling; Air-solid interface; Mesophase; Neutron diffractometry; Sodium dodecyl sulfate; Zirconia Air-solid interface; Neutron diffraction; Sodium dodecyl sulfate; Zirconium oxide
dc.titleSwelling of a mesostructured zirconium oxide film
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume385-386
dc.date.issued2006
local.identifier.absfor030603 - Colloid and Surface Chemistry
local.identifier.ariespublicationMigratedxPub13211
local.type.statusPublished Version
local.contributor.affiliationHenderson, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationRennie, Adrian R, Uppsala University
local.contributor.affiliationHawley, A, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWhite, John, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issuePart 1
local.bibliographicCitation.startpage713
local.bibliographicCitation.lastpage715
local.identifier.doi10.1016/j.physb.2006.05.305
dc.date.updated2015-12-12T07:50:16Z
local.identifier.scopusID2-s2.0-33751323926
CollectionsANU Research Publications

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