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A formal total synthesis of the marine diterpenoid diisocyanoadociane

Fairweather, Kelly Ann; Mander, Lewis

Description

A formal total synthesis of diisocyanoadociane, a marine diterpenoid with potent antimalarial properties, has been completed. The synthesis begins with a phenanthrenoid precursor that is transformed into a pyrene-derived intermediate by means of an intramolecular Michael reaction. Nitrogen functionality is introduced via a double Curtius reaction.

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
URI: http://hdl.handle.net/1885/84976
Source: Organic Letters
DOI: 10.1021/ol061228f

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