Factors Affecting the Relative and Absolute Rates of β-Scission of Alkoxythiocarbonyl Radicals and Alkoxycarbonyl Radicals
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Coote, Michelle; Easton, Christopher; Zard, Samir
Description
High-level ab initio calculations demonstrate that alkoxythiocarbonyl radicals (ROC.=S) undergo β-scission significantly faster than alkoxycarbonyl radicals (ROC.=O) despite having similar exothermicities. The relatively low reactivity of the ROC.=O radi
Collections | ANU Research Publications |
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Date published: | 2006 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/84917 |
Source: | Journal of Organic Chemistry |
DOI: | 10.1021/jo0607313 |
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01_Coote_Factors_Affecting_the_Relative_2006.pdf | 83.24 kB | Adobe PDF | Request a copy |
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