HMB and Cp* ruthenium(II) complexes containing bis- and tris-(mercaptomethimazolyl)borate ligands: synthetic, X-ray structural and electrochemical studies (HMB = η 6 -C 6 Me 6 , Cp* = η 5 -C 5 Me 5 )
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Kuan, Seah Ling; Leong, Weng Kee; Goh, Lai Yoong; Webster, Richard
Description
The reactions of [(HMB)RuCl2]2 with K[HB(mt) 3] and Na[H2B(mt)2] (mt = N-methyl-2- mercaptoimidazol-1-yl) led to the isolation of [(HMB)Ru{HB(mt)3}]Cl (1) (ca. 66% yield) and [(HMB)Ru{H2B(mt)2}]Cl (2) (ca. 70% yield), respectively. The reaction of [Cp*RuOMe]2 with Na[H2B(mt)2] yielded Cp*Ru[H2B(mt) 2] (3) (ca. 85% yield). Single crystal X-ray diffraction analyses were carried out on all three complexes, together with cyclic voltammetric measurements.
dc.contributor.author | Kuan, Seah Ling | |
---|---|---|
dc.contributor.author | Leong, Weng Kee | |
dc.contributor.author | Goh, Lai Yoong | |
dc.contributor.author | Webster, Richard | |
dc.date.accessioned | 2015-12-13T23:01:31Z | |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | http://hdl.handle.net/1885/84467 | |
dc.description.abstract | The reactions of [(HMB)RuCl2]2 with K[HB(mt) 3] and Na[H2B(mt)2] (mt = N-methyl-2- mercaptoimidazol-1-yl) led to the isolation of [(HMB)Ru{HB(mt)3}]Cl (1) (ca. 66% yield) and [(HMB)Ru{H2B(mt)2}]Cl (2) (ca. 70% yield), respectively. The reaction of [Cp*RuOMe]2 with Na[H2B(mt)2] yielded Cp*Ru[H2B(mt) 2] (3) (ca. 85% yield). Single crystal X-ray diffraction analyses were carried out on all three complexes, together with cyclic voltammetric measurements. | |
dc.publisher | Elsevier | |
dc.source | Journal of Organometallic Chemistry | |
dc.subject | Keywords: Boron compounds; Catalysts; Complexation; Cyclic voltammetry; Electrochemistry; Reaction kinetics; Single crystals; Sodium; Structure (composition); Synthesis (chemical); X ray diffraction analysis; (Mercaptomethimazolyl)borate; /(HMB)ruthenium; Cp; Ru[H< (Mercaptomethimazolyl)borate; Cp*/(HMB)ruthenium; Electrochemistry; Scorpionate; Structures | |
dc.title | HMB and Cp* ruthenium(II) complexes containing bis- and tris-(mercaptomethimazolyl)borate ligands: synthetic, X-ray structural and electrochemical studies (HMB = η 6 -C 6 Me 6 , Cp* = η 5 -C 5 Me 5 ) | |
dc.type | Journal article | |
local.description.notes | Imported from ARIES | |
local.description.refereed | Yes | |
local.identifier.citationvolume | 691 | |
dc.date.issued | 2006 | |
local.identifier.absfor | 030604 - Electrochemistry | |
local.identifier.ariespublication | MigratedxPub12739 | |
local.type.status | Published Version | |
local.contributor.affiliation | Kuan, Seah Ling, National University of Singapore | |
local.contributor.affiliation | Leong, Weng Kee, National University of Singapore | |
local.contributor.affiliation | Goh, Lai Yoong, National University of Singapore | |
local.contributor.affiliation | Webster, Richard, College of Physical and Mathematical Sciences, ANU | |
local.description.embargo | 2037-12-31 | |
local.bibliographicCitation.issue | 5 | |
local.bibliographicCitation.startpage | 907 | |
local.bibliographicCitation.lastpage | 915 | |
local.identifier.doi | 10.1016/j.jorganchem.2005.10.043 | |
dc.date.updated | 2015-12-12T07:40:49Z | |
local.identifier.scopusID | 2-s2.0-31644437449 | |
Collections | ANU Research Publications |
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