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Ligand rotation in [Ar(R)N] 3 M-N 2 -M[N(R)Ar] 3 (M, M = Mo III ,Nb III ; R = i Pr and t Bu) dimers

Christian, Gemma; Stranger, Robert; Yates, Brian F; Graham, David C.

Description

Earlier calculations on the model N2-bridged dimer (μ-N 2)-{Mo[NH2]3}2 revealed that ligand rotation away from a trigonal arrangement around the metal centres was energetically favourable resulting in a reversal of the singlet and triplet energies such t

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/84314
Source: Dalton Transactions
DOI: 10.1039/b413766c

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