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CH 2 CHOH 2 + + PN: A Proton-Transfer Triple Play

Petrie, Simon

Description

Quantum chemical calculations are used to explore the proton-transfer reactivity of O-protonated vinyl alcohol, CH2CHOH2+, with phosphorus nitride, PN. This reaction is relevant to the chemical evolution of interstellar clouds, since O-protonated vinyl alcohol has been postulated (and tentatively identified) as a product of the association reaction between interstellar H3O+ and C2H 2, while PN is the most widespread and abundant phosphorus-containing molecule seen in astrophysical environments....[Show more]

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/83193
Source: Journal of Physical Chemistry A
DOI: 10.1021/jp0507389

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