Zhu, Tao; Jackson, William Gregory; Hockless, David; Willis, Anthony
The kinetics and stereochemistry for the base catalysed substitution reactions of all seven isomers (4 mer and 3 fac) of both [Co(dien)(ibn)Cl]2+ and [Co(dien)(ampy)Cl]2+ have been studied in detail, for water and azide ion as entering groups. The stereochemistry for the azide ion anation of some of the [Co(dien)(diamine)OH]2+ species have also been investigated. The mer isomers are of comparable reactivity and amongst the fastest reacting pentaaminechlorocobalt(III) complexes known. They are...[Show more]
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