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The kinetics and stereochemistry of base hydrolysis of the seven isomers of [Co(dien)(ampy)Cl] 2+ and [Co(dien)(ibn)Cl] 2+

Zhu, Tao; Jackson, William Gregory; Hockless, David; Willis, Anthony

Description

The kinetics and stereochemistry for the base catalysed substitution reactions of all seven isomers (4 mer and 3 fac) of both [Co(dien)(ibn)Cl]2+ and [Co(dien)(ampy)Cl]2+ have been studied in detail, for water and azide ion as entering groups. The stereochemistry for the azide ion anation of some of the [Co(dien)(diamine)OH]2+ species have also been investigated. The mer isomers are of comparable reactivity and amongst the fastest reacting pentaaminechlorocobalt(III) complexes known. They are...[Show more]

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
URI: http://hdl.handle.net/1885/83033
Source: Inorganica Chimica Acta
DOI: 10.1016/j.ica.2005.11.050

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