The kinetics and stereochemistry of base hydrolysis of the seven isomers of [Co(dien)(ampy)Cl] 2+ and [Co(dien)(ibn)Cl] 2+
The kinetics and stereochemistry for the base catalysed substitution reactions of all seven isomers (4 mer and 3 fac) of both [Co(dien)(ibn)Cl]2+ and [Co(dien)(ampy)Cl]2+ have been studied in detail, for water and azide ion as entering groups. The stereochemistry for the azide ion anation of some of the [Co(dien)(diamine)OH]2+ species have also been investigated. The mer isomers are of comparable reactivity and amongst the fastest reacting pentaaminechlorocobalt(III) complexes known. They are...[Show more]
|Collections||ANU Research Publications|
|Source:||Inorganica Chimica Acta|
|01_Zhu_The_kinetics_and_2006.pdf||550.93 kB||Adobe PDF||Request a copy|
Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.