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A less carbocentric view of agostic interactions: the complexes [Rh( η 4 -cod){H 2 A(mt) 2 }] (A = B, C + ; mt = Methimazolyl).

Crossley, Ian R; Hill, Anthony; Humphrey, Elizabeth; Smith, Matthew


The reaction of [Rh2(μ-Cl)2(cod)2] (cod = 1,5-cyclooctadiene) with Na[H2B(mt)2] (mt = methimazolyl) provides the complex [Rh(cod){H2B(mt)2}] (1), which in turn reacts with CO or CNC6H3Me 2-2,6 to provide the derivatives [RhL2{H 2B(mt)2}] (L = CO (2), CNC

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: Organometallics
DOI: 10.1021/om050942i


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